Mn-Pr (Manganese-Praseodymium)
نویسندگان
چکیده
منابع مشابه
Praseodymium(III) sulfate hydroxide, Pr(SO4)(OH)
The title compound, Pr(SO(4))(OH), obtained under hydro-thermal conditions, consists of Pr(III) ions coordinated by nine O atoms from six sulfate groups and three hydroxide anions. The bridging mode of the O atoms results in the formation of a three-dimensional framework, stabilized by two O-H⋯O hydrogen-bonding inter-actions.
متن کاملPraseodymium valency from crystal structure in Pr-Ba-Cu-O and (Y-Pr)-Ba-Cu-O single crystals
2014 The substitution of Pr to Y leads to materials with a general formula (Y1-vPrv)(Ba2-x’Prx’)(Cu3-y~y)O6+x’/ 2-y+z and with a structural transition around x = v + x’ ~ 0.5. For x ~ 0.5 the crystals are orthorhombic, Y-Ba-Cu-O type, but with a lowered distortion. For v ~ 0.5 the crystals are tetragonal, La1.5Ba1.5Cu3O7 ± z type, with the characteristic tri-twinning of this phase. The Pr valen...
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Bacterial manganese (Mn) oxidation plays an important role in the global biogeochemical cycling of Mn and other compounds, and the diversity and prevalence of Mn oxidizers have been well established. Despite many hypotheses of why these bacteria may oxidize Mn, the physiological reasons remain elusive. Intracellular Mn levels were determined for Pseudomonas putida GB-1 grown in the presence or ...
متن کاملExperimental lifetime determination in neutral praseodymium (Pr I) and neodymium (Nd I)
Radiative lifetime measurements have been performed, with a time-resolved laser-induced fluorescence technique, for 18 even-parity levels of Pr I and 15 odd-parity levels of Nd I. The new results are compared with the few experimental data available in the literature and good agreement is found. However, fragmentary knowledge of the spectra prevents reliable calculation of branching fractions a...
متن کاملEmployment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: Mn(II)(2)Mn(IV) and Mn(II)(2)Mn(III)(6) complexes.
The employment of the anion of methyl 2-pyridyl ketone oxime (mpko(-)) as a tridentate chelating/bridging ligand in manganese chemistry is described. The inorganic anion (Br(-), ClO(4)(-)) used in the reaction affects the identity of the product. The reaction of MnBr(2) and one equivalent of mpkoH in the presence of a base affords [Mn(3)(OMe)(2)(mpko)(4)Br(2)] (3), which is mixed-valence (2Mn(I...
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ژورنال
عنوان ژورنال: Journal of Phase Equilibria and Diffusion
سال: 2011
ISSN: 1547-7037,1863-7345
DOI: 10.1007/s11669-011-9880-3